Articles
Mechanistic insight into the ferritization of austenite in Pb via a discontinuous reaction governed by a migrating liquid film
Corrosion Science 258 (2026) 113398
Kin Wing Wong, Peter Szakálos, Christopher Petersson, Dmitry Grishchenko, Pavel Kudinov
2025-10-15
Abstract
The dissolution of austenitic steel in liquid lead-based alloys can induce a phase transformation characterized by a sharp dissolution front separating ferrite and austenite grains, a process commonly referred to as ferritization. Although widely reported, the mechanism driving this transformation remains under debate. This study re-examines ferritization as a discontinuous reaction via a migrating liquid film and proposes a thermodynamically consistent model for the initiation and propagation of the dissolution front. The proposed mechanism is supported by experiments at 500–550°C, literature evidence, and diffusion calculations. Under low oxygen conditions, Cr transport through liquid Pb channels is identified as the rate-limiting step, setting the theoretical corrosion rate in stagnant environments. High-speed erosion-corrosion tests show enhanced corrosion rates, driven by erosion-limited channel lengths that locally boost mass transport. In contrast, under moderate oxygen concentrations relevant for lead-cooled fast reactor (LFR) operation, the rate-limiting step shifts to metal transport across a nanometer-scale amorphous oxide layer at the reaction front. Other Ni-containing austenitic steels, including alumina-forming austenitic (AFA) alloys and Ni-based high-entropy alloys (HEAs) can also be susceptible to discontinuous reactions under direct contact with liquid Pb-based alloys, lacking the self-healing oxide protection as observed in alumina-forming ferritic steels. This limitation may present a concern for the long-term use of bare austenitic steel in liquid Pb environments.
Irradiation-induced polymorphism in Fe–Cr alloys
Scientific Reports 15 (2025) 35050
Ebrahim Mansouri, Xiaoqing Li, Pär Olsson
2025-10-08
Abstract
Direct damage evolution simulations based on electronic structure physics show a significant correlation between Cr concentration and polymorphism in the form of localized formation of C15 Laves phase structures in Fe–Cr alloys under irradiation. We elucidate the role of Cr content in the formation and stabilization of the C15 Laves phase structure, which is crucial to understanding the behavior of materials under extreme conditions. This study also reveals a connection between non-linear magnetic behavior and irradiation-induced swelling in Fe–Cr alloys. These results advance the comprehension of radiation-induced changes in magnetization and suggest a novel experimental approach for detecting C15 clusters in irradiated Fe–Cr alloys.
Assessing the near-surface diffusion of Xe and Kr in Zirconia by time-of-flight elastic recoil detection analysis
Nuclear Instruments and Methods in Physics Research B 566 (2025) 1657736
N. Wikström, M. Giamouridou, E. Charatsidou, P. Olsson, J. Oscarsson, D. Primetzhofer, R.J.W. Frost
2025-06-06
Abstract
The diffusion of two volatile fission products, xenon (Xe) and krypton (Kr), in zirconia (ZrO2) is investigated. Samples of Yttria (Y2O3)-stabilised tetragonal ZrO2 were implanted with either Xe or Kr, at 300 keV, with a fluence of 10¹⁷ at./cm2, and subsequently analysed with time-of-flight elastic recoil detection analysis (ToF-ERDA) to obtain elemental composition depth profiles. Samples were then annealed at 1200 ◦C for 9 h, and the effect of the annealing was assessed by ToF-ERDA measurements. From these measurements, first-order approximations of diffusion coefficients for Xe and Kr in ZrO2 were derived, using a model based on Fick’s second law, these being (1.36 ± 0.87) × 10⁻¹⁹ m²/s and (2.94 ± 1.96) × 10⁻¹⁹ m²/s at 1200 ◦C for Kr and Xe respectively. It was shown that ToF-ERDA can provide data to analyse the diffusion of elements in solid sample matrices and that a model based on Fick’s Law can predict the diffusion of the implanted ions.