Lectures and tutorials.
FCK3307 Molecular Thermodynamics 7.5 credits
The power of thermodynamics is its generality. This course deals with the microscopic and molecular origin of the mechanisms on which thermodynamics is based. In this course we develop a basic knowledge in statistical thermodynamics to understand the forces that drive molecules and to be able to predict their combined behavior in physical, chemical, and biological systems.
Information for research students about course offerings
The course is given annually. Contact the examiner for information.
Choose semester and course offering
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Application
For course offering
Spring 2024 Start 16 Jan 2024 programme students
Application code
60872
Headings with content from the Course syllabus FCK3307 (Spring 2020–) are denoted with an asterisk ( )
Content and learning outcomes
Course disposition
Course contents
- Principles of probability.
- The Boltzmann distribution law.
- The statistical mechanics of simple gases and solids and the molecular interpretation of temperature and heat capacity.
- Chemical and phase equilibria.
- Solutions, mixtures and transfer of molecules between phases.
- Physical (i.e. diffusion, permeation and flow) and chemical kinetics.
- Electrostatics: Coulomb’s Law, electrostatic potential and electrochemical equilibria.
- Intermolecular interactions and phase transitions.
- Adsorption, binding and catalysis.
- Thermodynamic properties of water
- Introduction to the thermodynamics of polymer solutions.
Intended learning outcomes
After completion of the course the student should have the knowledge and ability to
- Reflect over and describe in detail microscopic models and basic relationships in terms of entropy and enthalpy contributions that together determine the free energy for different molecular systems.
- Use the resulting formalism and concepts to describe and explain macroscopic behaviour in different materials and systems.
Literature and preparations
Specific prerequisites
Eligible for studies at the third-cycle level.**
Recommended prerequisites
No information inserted
Equipment
No information inserted
Literature
Ken A. Dill and Sarina Bromberg, Molecular Driving Forces, 2nd Edition, Garland Science.
Examination and completion
If the course is discontinued, students may request to be examined during the following two academic years.
Grading scale
P, F
Examination
- TEN1 - Written exam, 7.5 credits, grading scale: P, F
Based on recommendation from KTH’s coordinator for disabilities, the examiner will decide how to adapt an examination for students with documented disability.
The examiner may apply another examination format when re-examining individual students.
Opportunity to complete the requirements via supplementary examination
No information inserted
Opportunity to raise an approved grade via renewed examination
No information inserted
Examiner
Ethical approach
- All members of a group are responsible for the group's work.
- In any assessment, every student shall honestly disclose any help received and sources used.
- In an oral assessment, every student shall be able to present and answer questions about the entire assignment and solution.
Further information
Course room in Canvas
Registered students find further information about the implementation of the course in the course room in Canvas. A link to the course room can be found under the tab Studies in the Personal menu at the start of the course.
Offered by
Main field of study
This course does not belong to any Main field of study.
Education cycle
Third cycle
Add-on studies
No information inserted
Contact
Eric Tyrode