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Mårten Ahlquist

Profilbild av Mårten Ahlquist

PROFESSOR

Detaljer

Adress
MALVINAS VÄG 10

Om mig

NEWS

2018-11-26 - Check out our JACS paper

2017-03-31 - Paper Accepted in Angewandte Chemie!
New paper "Capturing the Role of Explicit Solvent in the Dimerization of RuV(bda) Water Oxidation Catalysts" accepted. Describes the interaction of the catalysts with solvent molecules along the O-O bond forming reaction. Available here.

2016-11-16 - New paper "Why Is There a Barrier in the Coupling of Two Radicals in the Water Oxidation Reaction?" out in ACS Catalysis. Available here.

TOC-I2M
2016-11-01 - 
Welcome to our new PhD student Xiaoyu Chen

2016-10-15 - We received 36 Msek grant for new catalytic materials! Read more here

2016-10-03 - JACS paper from collaboration with Belén Martín-Matute published here!

2016-08-09 - New paper in Organometallics out. Magazine cover ! Available here

2016-04-08 - New paper in ACS Catalysis out. Available here

ACS Catal CO2 reduction solvent

2015-09-07 - New group member. We welcome Shaoqi Zhan to our group!

2015-06-29 - HOT PAPER! Paper published online in Angewandte Chemie appointed as hot paper. Available here.

Alpha alkyl migration

2015-05-22 - Paper accepted in ACS Catalysis on epoxidation of alkenes by ruthenium catalysts with carboxylated ligands. Available on the ACS websiteACS Catalysis 2015

2015-05-08 - Paper accepted in Angewandte Chemie! More info soon.

2015-03-07 - Paper on reversible multiple CH activations at an iridium complex published in Chemical Science

Chemical Science 2015

Research

Our research

Our research is focused on the reaction mechanisms and properties of transition metal complexes. Due to their versatile and tunable reactivity such well defined complexes have been successfully used as catalysts for stereospecific synthesis of pharmaceuticals, for polymerization with high specificity, and for synthesis of bulk chemicals. We are currently investigating catalysts that could be used for storage of energy, which is crucial for large scale implementation of sustainable energy sources. When solar energy is used such energy storage is called artificial photosynthesis. The three main reactions of interest is 1) water oxidation to split water into gaseous oxygen, protons and electrons 2) proton reduction to combine the electrons and protons to hydrogen gas 3) carbon dioxide hydrogenation to formic acid, or methanol, as a way of storing the hydrogen in liquid form.

ch activation

Another class of compounds that we are investigating are alkanes. Today alkanes are mainly burned for energy. An attracive alternative use is as starting material for functional materials. Since alkanes are fully saturated C-H bonds need to be activated. Due to their apolar nature and the strength of the bonds these processes are typically very challenging. Moreover, a catalyst for such reaction needs to be completely selective towards specific C-H bonds in the reactant, and not react with other bonds or further react with the product to degrade it. Our work is focused on quantum chemical modeling of the catalysts to understand their properties and to further improve their reactivity and selectivity.

Education

M.Sc. in Chemistry 2004
Lund University

Ph.D. in Chemistry 2007
DTU Technical University of Denmark

Postdoc 2007-2009
California Institute of Technology

Docent 2013
KTH

Employments

Wallenberg repatriation 2009-2011
KTH

Assistant Professor (Vetenskapsrådet) 2011-2014
KTH

Associate Professor 2014-
KTH


Kurser

Aktuell litteratur i teoretisk kemi och biologi (FBB3480), examinator | Kurswebb

Forskningspresentation i teoretisk kemi och biologi (FBB3470), examinator | Kurswebb

Fysikalisk biokemi (KD1500), examinator, kursansvarig | Kurswebb

Molekylär modellering (BB2280), examinator, kursansvarig | Kurswebb

Molekylär modellering (FCB3204), examinator, kursansvarig, lärare | Kurswebb

Projekt i kemi (KD2905), examinator | Kurswebb